49.

Mono- and Di-Cationic Hydrido Boron Compounds.
Ghadwal,* Rajendra S.; Schuermann, Christian J.; Andrada, Diego M.; Frenking, Gernot.
Dalton Trans., 2015, 44, 14359-14367.

48.

Palladium Catalyzed Direct C2-Arylation of an N-Heterocyclic Carbene: An Atom-Economic Route to Mesoionic Carbene Ligands.
Ghadwal,* Rajendra S.; Reichmann, Sven O.; Herbst-Irmer, Regine.
Chem. Eur. J., 2015, 21, 4247-4251.

47.

Synthesis and Structural Investigation of R₂Si (R = Me, Ph) Bridged Di-N-Heterocyclic Carbenes.
Ghadwal,* Rajendra S.; Reichmann, Sven O.; Carl, Elena; Herbst-Irmer, Regine.
Dalton Trans., 2014, 43, 13704-13710.

46.

Unprecedent Borylene Insertion into a C-N Bond.
Ghadwal,* Rajendra S.; Schuermann, Christian J.; Engelhardt, Felix,; Steinmetzger, Christian.
Eur. J. Inorg. Chem., 2014, 4921-4926.

Cover Profile: Eur. J. Inorg. Chem. 2014, 4908, Issue 29.

Front Cover Picture: Eur. J. Inorg. Chem. 2014, Issue 29.

45.

Facile Access to Silyl-Functionalized N-Heterocyclic Olefins with HSiCl₃
Ghadwal,* Rajendra S.; Reichmann, Sven O.; Engelhardt, Felix,; Andrada, Diego M.; Frenking, Gernot.
Chem. Commun., 2013, 49, 9440-9442.

44.

Selective Functionalization of a Bis-silylene
Ghadwal,* Rajendra S.; Azhakar, Ramachandran; Proepper, Kevin; Dittrich, Birger; John, Michael.
Chem. Commun., 2013, 49, 5987-5989.

43.

Mixed Valence η6–Arene Cobalt(I) and Cobalt(II) Compounds.
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Hey, Jakob; Krause, Lennard; Stalke,* Dietmar.
Dalton. Trans., 2013, 42, 10277-10281.

42.

Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block.
Ghadwal,* Rajendra S.; Azhakar, Ramachandran; Roesky,* Herbert W.
Acc. Chem. Res., 2013, 46, 444-456.

41.

Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of Silicon-Sulfur Three- (Si-C-S) and Five- (Si-C-C-C-S) Membered Ring Systems.
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Mata, Ricardo A.; Wolf, Hilke; Herbst-Irmer, Regine; Stalke,* Dietmar.
Chem. Eur. J. 2013,19, 3715-3720.

40.

Stable Silaimines with Three- and Four-Coordinate Silicon Atoms.
Samuel, Prinson P.; Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Sen, Sakya S.; Roesky,* Herbert W.; Granitzka, Markus; Matussek, Julia; Herbst-Irmer, Regine; Stalke,* Dietmar.
Inorg. Chem., 2012, 51, 11049-11054.

39.

An access to base-stabilized three-membered silicon heterocycles.
Azhakar, Ramachandran; Roesky,* Herbert W.; Ghadwal,* Rajendra S.; Holstein, Julian J.; Dittrich,* Birger.
Dalton Trans., 2012, 41, 9601-9603.

38.

Donor-acceptor stabilized silaformyl chloride.
Ghadwal,* Rajendra S.; Azhakar, Ramachandran; Roesky,* Herbert W.; Proepper, Kevin; Dittrich,* Birger; Goedecke, Catharina; Frenking,* Gernot.
Chem. Commun., 2012, 48, 8186-8188.

37.

Reactivity studies of a stable N-heterocyclic silylene with triphenylsilanol and pentafluorophenol.
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Granitzka, Markus; Stalke,* Dietmar.
Organometallics, 2012, 31, 5506-5510.

36.

Lewis base mediated dismutation of trichlorosilane.
Singh, Amit Pratap; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Holstein, Julian J.; Dittrich,* Birger; Demers, Jean-Philippe; Chevelkov, Veniamin; Lange, Adam.
Chem. Commun., 2012, 48, 7574-7576.

35.

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)₂SiX (X = PPh₂, NPh₂, NCy₂, NiPr₂, NMe₂, N(SiMe₃)₂, OtBu).
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Wolf, Hilke; Stalke,* Dietmar.
Organometallics, 2012, 31, 4588-4592.

34.

A debut for base stabilized monoalkylsilylenes.
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Wolf, Hilke; Stalke,* Dietmar.
Chem. Commun., 2012, 48, 4561-4563.

33.

Double N-H bond activation of N,N'-bis-substituted hydrazines with stable N-heterocyclic silylene.
Azhakar, Ramachandran; Ghadwal, Rajendra S.; Roesky, Herbert W.; Hey, Jakob; Stalke, Dietmar.
Dalton Trans., 2012, 41, 1529-1533.

32.

Stabilization of Low Valent Silicon Fluorides in the Coordination Sphere of Transition Metals.
Azhakar, Ramachandran; Ghadwal,* Rajendra S.; Roesky,* Herbert W.; Wolf, Hilke; Stalke,* Dietmar.
J. Am. Chem. Soc., 2012, 134, 2423-2428.

31.

Donor-Acceptor-Stabilized Silicon Analogue of an Acid Anhydride.
Ghadwal,* Rajendra S.; Azhakar, Ramachandran; Roesky,* Herbert W.; Proepper, Kevin; Dittrich,* Birger; Klein, Susanne; Frenking,* Gernot.
J. Am. Chem. Soc., 2011,133, 17552-17555.

30.

Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium.
Percival, Paul W.; Brodovitch, Jean-Claude; Mozafari, Mina; Mitra, Amitabha; West, Robert; Ghadwal, Rajendra S.; Azhakar, Ramachandran; Roesky, Herbert W.
Chem. Eur- J., 2011, 17, 11970-11973.

29.

N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0).
Ghadwal,* Rajendra S.; Azhakar, Ramachandran; Proeper, Kevin; Holstein, Julian J.; Dittrich,* Birger; Roesky,* Herbert W.
Inorg. Chem., 2011, 50, 8502-8508.

28.

Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone.
Azhakar, Ramachandran; Ghadwal, Rajendra S.; Roesky, Herbert W.; Hey, Jakob; Stalke, Dietmar,
Organometallics, 2011, 30, 3853-3858.

27.

A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms.
Ghadwal, Rajendra S.; Roesky, Herbert W.; Proepper, Kevin; Dittrich, Birger; Klein, Susanne; Frenking, Gernot,
Angew. Chem. Int. Ed., 2011, 50, 5374-5378.Selected as VIP

Highlighted in: Angew. Chem. Int. Ed. 2011, 50, 9020-9022

26.

Synthesis and Structure of [{PhC(NtBu)₂}₂Ge₂(μ-S)₂Cl₂] and a Germanium Dithiocarboxylate Analogue.
Sen, Sakya S.; Ghadwal, Rajendra S.; Kratzert, Daniel; Stern, Daniel; Roesky, Herbert W.; Stalke, Dietmar,
Organometallics, 2011, 30, 1030-1033.

25.

Neutral Pentacoordinate Silicon Fluorides Derived from Amidinate, Guanidinate, and Triazapentadienate Ligands and Base-Induced Disproportionation of Si₂Cl₆ to Stable Silylenes.
Ghadwal, Rajendra S.; Proepper, Kevin; Dittrich, Birger; Jones, Peter G.; Roesky, Herbert W.,
Inorg. Chem., 2011, 50, 358-364.

24.

N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr•Cl₂Si=NR.
Ghadwal, R. S.; Roesky, H. W.; Granitzka, M. and Stalke D.
Organometallics 2010, 29, 6329-6333.

23.

Facile Route to Functionalized N-Heterocyclic Carbene (NHC) with NHC Base Stabilized Dichlorosilylene.
Ghadwal, R. S.; Roesky, H. W.; Granitzka, M. and Stalke D.
J. Am. Chem. Soc., 2010, 132, 10018-10020.

22.

Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon.
Ghadwal, Rajendra S.; Sen, Sakya S.; Roesky, Herbert W.; Granitzka, Markus; Kratzert, Daniel; Merkel, Sebastian; Stalke, Dietmar.
Angew. Chem. Int. Ed., 2010, 49, 3952-3955.

21.

Ambiphilicity of Dichlorosilylene in a Single Molecule.
Ghadwal, , Rajendra S.; Roesky, Herbert W.; Merkel, Sebastian; Stalke, Dietmar.
Chem. Eur.-J., 2010,16, 85-88.

20.

Ambiphilicity Lewis-Base-Stabilized Dichlorosilylene: A Two-Electron σ-Donor Ligand.
Li, Jianfeng; Merkel, Sebastian; Henn, Julian; Meindl, Kathrin; Doring, Alexander; Roesky, Herbert W.; Ghadwal, Rajendra S.; Stalke, Dietmar,
Inorg. Chem., 2010, 49, 775-777.

19.

Neutral Penta- and Hexacoordinate N-Heterocyclic Carbene Complexes Derived from SiX₄ (X = F, Br).
Ghadwal, Rajendra S.; Sen, Sakya S.; Roesky, Herbert W.; Tavcar, Gasper; Merkel, Sebastian; Stalke, Dietmar.
Organometallics, 2009, 28, 6374-6377.

18.

Lewis Base Stabilized Dichlorosilylene.
Ghadwal, Rajendra S.; Roesky, Herbert W.; Merkel, Sebastian; Henn, Julian; Stalke, Dietmar.
Angew. Chem. Int. Ed., 2009, 48, 5683-5686.

17.

N-Heterocyclic carbene adducts of aluminum triiodide.
Ghadwal, Rajendra S.; Roesky, Herbert W.; Herbst-Irmer, Regine; Jones, Peter G.
Z. Anorg. Allg. Chem., 2009, 635, 431-433.