Publications


Cover



2019


"Selectivity of Tungsten Mediated Dinitrogen Splitting vs. Proton Reduction" B. Schluschaß, J. Abbenseth, S. Demeshko, M. Finger, A. Franke, C. Herwig, C. Würtele, I. Ivanovic-Burmazovic, C. Limberg, Joshua Telser, S. Schneider, Chem. Sci. 2019, DOI: 10.1039/C9SC03779A.
Part of "2019 Chemical Science HOT Article Collection"

"Oxidative Coupling of Terminal Rhenium Pnictide Complexes" J. Abbenseth, M. Diefenbach, A. Hinz, L. Alig, C. Würtele, J. M. Goicoechea, M. Holthausen, S. Schneider, Angew. Chem. Int. Ed. 2019, 58, 10971-10974.

"A Terminal Iridium Oxo Complex with a Triplet Ground State" D. Delony, M. Kinauer, M. Diefenbach, S. Demeshko, C. Würtele, M. C. Holthausen, S. Schneider Angew. Chem. Int. Ed., 2019, 58, 10966-10970.
ChemViews Magazine Highlight Article.

"Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer" J. Abbenseth, D. Delony, M. C. Neben, C. Würtele, B. de Bruin, S. Schneider, Angew. Chem. Int. Ed. 2019, 58, 6338 –6341.

"First-Row Transition Metal (De)hydrogenation Catalysis based on Functional Pincer Ligands" L. Alig, M. Fritz, S. Schneider Chem. Rev., 2019, 119, 2681-2751..

"Metal-Ligand Cooperative Synthesis of Benzonitrile via Electrochemical Reduction and Photolytic Splitting of Dinitrogen" F. Schendzielorz, M. Finger, J. Abbenseth, C. Würtele, V. Krewald, S. Schneider Angew. Chem. Int. Ed., 2019, 58, 830-834.

2018


"Hydrosilane Synthesis by Catalytic Hydrogenolysis of Chlorosilanes and Silyl Triflates" A. Glüer, J. Schweizer, U. Karaca, C. Würtele, M. Diefenbach, M. Holthausen, S. Schneider Inorg. Chem., 2018, 57, 13822-13828..

"Synthesis of Benzonitrile from Dinitrogen" I. Klopsch, F. Schendzielorz, C. Volkmann, C. Würtele, S. Schneider Z. Anorg. Allg. Chem., 2018, 644, 916-919 (Cover Feature)

"Mechanism of Chemical and Electrochemical N2 Splitting by a Rhenium Pincer Complex" B. M. Lindley, R. S. van Alten, M. Finger, F. Schendzielorz, C. Würtele, A. J. M. Miller, I. Siewert, S. Schneider J. Am. Chem. Soc., 2018, 140, 7922-7935.

"Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex" F. Schneck, F. Schendzielorz, N. Hatami, M. Finger, C. Würtele, S. Schneider Angew. Chem. Int. Ed., 2018, 57, 14482-14487.
(Open Access, Frontispiece).

"Inelastic H Atom Scattering from Ultrathin Aluminum Oxide Films Grown by Atomic Layer Deposition on Pt(111)" Y. Dorenkamp, C. Volkmann, V. Roddatis, S. Schneider, A. M. Wodtke, O. Bünermann J. Phys. Chem. C, 2018, 122, 10096-10102.

"An Iridium(III/IV/V) Redox Series featuring a terminal Imido Complex with Triplet Ground State " M. Kinauer, M. Diefenbach, H. Bamberger, S. Demeshko, E. J. Reijerse, C. Volkmann, C. Würtele, J. van Slageren, B. de Bruin, M. C. Holthausen, S. Schneider Chem. Sci., 2018, 9, 4325-4332.
(Open Access)

"Process for the Generation of Thin Inorganic Films" T. Adermann, F. Abels, C. Limburg, H. Wilmer, J. Gerkens, S. Schneider WO2018041695 (A1), 2018.

"Iron Catalyzed Hydrogenation and Electrochemical Reduction of CO2: The Role of Functional Ligands" A. Glüer, S. Schneider, J. Organomet. Chem. 2018 861, 159-173. (invited review article on behalf of W.A. Herrmann’s 70th birthday)

"The Elusive Abnormal CO2 Insertion Enabled by Metal-Ligand Cooperative Photochemical Selectivity Inversion" F. Schneck, J. Ahrens, M. Finger, A. C. Stückl, C. Würtele, D. Schwarzer S. Schneider, Nat. Commun. 2018 9, 1161.
(Open Access)

"A Ruthenium Hydrido Dinitrogen Core Conserved Across Multielectron/Multiproton Changes to the Pincer Ligand Backbone" Q. Bruch, B. Lindley, B. Askevold, S. Schneider, A. Miller Inorg. Chem. 2018, 57, 1964-1975.
(Open Access)

"Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”" J. Abbenseth, S. C. Bete, C. Volkmann, C. Würtele, S. Schneider Organometallics 2018, 37, 802-811.
(Open Access)

2017


"Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex" C. Rebreyend, Y. Gloaguen, M. Lutz, J. I. van der Vlugt, I. Siewert, S. Schneider, B. de Bruin Chem. Eur. J., 2017, 23, 17438 (Cover Feature).

"Author profile: Sven Schneider" Angew. Chem. Int. Ed., 2017, 56, 13180.

"Nitrene Radical Intermediates in Catalytic Synthesis" P. Kuijpers, J. I. van der Vlugt, S. Schneider, B. de Bruin, Chem. Eur. J., 2017, 23, 13819 (Frontispiece).

"Process for the Generation of Thin Inorganic Films" T. Adermann, D. Loeffler, H. Wilmer, K. Schierle-Arndt, J. Gerkens, C. Volkmann, S. Schneider, WO2017093283 (A1), 2017.

"Dinitrogen Splitting Coupled to Protonation" G. A. Silantyev, M. Förster, B. Schluschaß, J. Abbenseth, C. Würtele, C. Volkmann, M. C. Holthausen, S. Schneider, Angew. Chem. Int. Ed., 2017, 56, 5872-5876; Angew. Chem. , 2017, 129, 5966-5970.
(Open Access)

"A Square-Planar Osmium(II) Complex" J. Abbenseth, M. Diefenbach, S. C. Bete, C. Würtele, C. Volkmann, S. Demeshko, M. C. Holthausen, S. Schneider, Chem. Commun., 2017, 53, 5511-5514.
(Open Access)

"Functionalization of N2 by Mid to Late Transition Metals via N–N Bond Cleavage" I. Klopsch, E.Y. Yuzik-Klimova, S. Schneider, Topics in Organometallic Chemistry, 2017, 1-42.

"Chemical Non-Innocence of an aliphatic PNP Pincer Ligand." F. Schneck, M. Finger, M. Tromp, S. Schneider, Chem. Eur. J. 2017, 23, 33. (Frontispiece)
(Open Access)



2016


"A Terminal Osmium(IV) Nitride: Ammonia Formation and Ambiphilic Reactivity." F. S. Schendzielorz, M. Finger, C. Volkmann, C. Würtele, S. Schneider, Angew. Chem. Int. Ed. 2016, 55, 11417-11420.
(Open Access)

"Square-Planar Cobalt(III) Pincer Complex." P.O. Lagaditis, B. Schluschaß, S. Demeshko, C. Würtele, S. Schneider, Inorg. Chem. 2016, 55 (9), 4529-4536.

"Conversion of Dinitrogen into Acetonitrile under Ambient Conditions." I. Klopsch, M. Kinauer, M. Finger, C. Würtele, S. Schneider, Angew. Chem. Int. Ed. 2016, 55, 4786-4789.
(Open Access)

"Coupling of Terminal Iridium Nitrido Complexes." J. Abbenseth, M. Finger, C. Würtele, M. Kasanmascheff, S. Schneider, Inorg. Chem. Front. 2016, 3, 469-477. (Journal Cover)
(Open Access)

"A Disilene Base Adduct with a Dative Si-Si Single Bond." J. I. Schweizer, M. G. Scheibel, M. Diefenbach, F. Neumeyer, C. Würtele, N. Kulminskaya, R. Linser, N. Auer, S. Schneider, M. C. Holthausen, Angew. Chem. Int. Ed. 2016, 55, 1782-1786.



2015


"Highly Active Iron Catalyst for Ammonia Borane Dehydrocoupling at Room Temperature". A. Glüer, M. Förster, V. R. Celinski, J. Schmedt auf der Günne, M. C. Holthausen, S. Schneider, ACS Catalysis 2015, 5, 7214-7217.

"Oxygen Reduction with a Bifunctional Iridium Dihydride Complex". C. Schiwek, J. Meiners, M. Förster, C. Würtele, M. Diefenbach, M. C. Holthausen, S. Schneider, Angew. Chem. Int. Ed. 2015, 54, 1-6.

"N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species". M. G. Scheibel, J. Abbenseth, M. Kinauer, F. W. Heinemann, C. Würtele, B. de Bruin, S. Schneider, Inorg. Chem. 2015, 54 (19), 9290-9302.
(Open Access Publication)

"Square-Planar Ruthenium(II) Complexes: Control of Spin State by Pincer Ligand Functionalization". B. Askevold, M. M. Khusniyarov, W. Kroener, K. Gieb,P. Müller, E. Herdtweck, F. W. Heinemann, M. Diefenbach, M. C. Holthausen, V. Vieru, L. F. Chibotaru, S. Schneider, Chem. Eur. J. 2015, 21, 579-589. (Journal Cover)

"Electron-rich, Nitrido-bridged Ruthenium Complexes". A. Glüer, B. Askevold, B. Schluschaß, F. W. Heinemann, S. Schneider, Z. Allg. Anorg. Chem. 2015, 641, 49-51. (invited contribution)



2014


"Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones." S. Chakraborty, P. O. Lagaditis, M. Förster, E. A. Bielinski, N. Hazari, M. C. Holthausen,W. D. Jones, S. Schneider, ACS Catalysis 2014, 4, 3994-4003.

"Lewis Acid-Assisted Formic Acid Dehydrogenation Using a Pincer-Supported Iron Catalyst." E. A. Bielinski, P. O. Lagaditis, Y. Zhang, B. Q. Mercado, C. Würtele, W. H. Bernskoetter, N. Hazari, S. Schneider, J. Am. Chem. Soc. 2014, 136, 10234-10237.

"Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium". I. Klopsch, M. Finger, C. Würtele, B. Milde, D.B. Werz, S. Schneider, J. Am. Chem. Soc. 2014, 136, 6881-6883.

"An Isolated Nitridyl Radical-Brigdes {Rh(N)Rh} Complex". Y. Gloaguen, C. Rebreyend, M. Lutz, P. Kumar, M. Huber, J. I. van der Vlugt, S. Schneider, B. de Bruin, Angew. Chem. Int. Ed. 2014, 53, 6814-6818 (Journal Cover).

"[IrCl{N(CHCHPtBu2)2}]-: A versatile source for the IrI(PNP) pincer platform". M. Kinauer, M. G. Scheibel, J. Abbenseth, F. W. Heinemann, P. Stollberg, C. Würtele, S. Schneider, Dalton Trans. 2014, 43, 4506-4513.

"Synthesis and Structure of Six Coordinate Iron Borohydride Complexes Supported by PNP Ligands". I. Koehne, T. J. Schmeier, E. A. Bielinski, C. J. Pan, W. H. Bernskoetter, C. Würtele, M. K. Takase, N. Hazari, S. Schneider, Inorg. Chem. 2014, 744, 35-40.



2013


"Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium". M. G. Scheibel, Y. Wu, A. C. Stückl, L. Krause, E. Carl, D. Stalke, B. de Bruin, S. Schneider, J. Am. Chem. Soc., 2013, 135 (47), 17719-17722.

"The Mechanism of Borane-Amine Dehydrocoupling with Bifunctional Ruthenium Catalysts". A. N. Marziale, A. Friedrich, I. Klopsch, M. Drees, V. R. Celinski, J. Schmedt auf der Günne, S. Schneider, J. Am. Chem. Soc. 2013, 135, 13342.

"Thionitrosyl- and Selenonitrosyliridium Complexes". M. G. Scheibel, I. Klopsch, H. Wolf, P. Stollberg, D. Stalke, S. Schneider, Eur. J. Inorg. Chem. 2013, 20, 3454. (special issue on small molecule activation)

"Reactivity of Iridium(I) PNP amido complexes toward protonation and oxidation". B. Askevold, A. Friedrich, M. R. Buchner, B. Lewall, A. C. Filippou, E. Herdtweck, S. Schneider, J. Organomet. Chem. 2013, 744, 35. (special issue on behalf of W. A. Herrmann's 65th birthday)



2012


"Closed-Shell and Open-Shell, square-planar Iridium Nitrido Complexes." M. G. Scheibel, B. Askevold, F. Heinemann, E. I. Reijerse, B. de Bruin,* S. Schneider* Nature Chem, 2012, 4, 552.

"New Insights into the Biological and Synthetic Fixation of Nitrogen" M. Scheibel, S. Schneider* Angew. Chem., 2012, 124, 4605; Angew. Chem. Int. Ed. 2012, 51, 4529.

"Learnig from the Neighbours: Improving Homogeneous Catalysis with Functional Ligands motivated by Heterogeneous and Bio-catalysis." B. Askevold, H. W. Roesky,* S. Schneider*, ChemCatChem 2012, 4, 307.

"Cooperative Aliphatic PNP Amido Pincer Ligands – Versatile Building Blocks for Coordination Chemistry and Catalysis." S. Schneider*, J. Meiners, B. Askevold, Eur. J. Inorg. Chem. 2012, 412.



2011


"Square-Planar Iridium(II) and Iridium(III) Amido Complexes." J. Meiners, M. Scheibel, M.-H. Lemée-Cailleau, S. A. Mason, M. B. Boeddinghaus, T. F. Fässler, E. Herdtweck, M. M. Khusniyarov,* S. Schneider* Angew. Chem. 2011, 123, 8334; Angew. Chem. Int. Ed. 2011, 50, 8184.

"Ammonia formation by metal-ligand cooperative hydrogenolysis of a nitrido ligand." B. Askevold, J. Torres Nieto, S. Tussupbayev, M. Diefenbach, E. Herdtweck, M. C. Holthausen,* S. Schneider* Nature. Chem.2011, 3, 532.



2010


"Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes." A. Staubitz, M. Sloan, A. Robertson, A. Friedrich, S. Schneider, P. Gates, J. Schmedt auf der Günne, I. Manners* J. Am. Chem. Soc. 2010, 132, 13332.

"A Square-Planar Ruthenium(II) Complex with a Low-Spin Configuration." B. Askevold, M. M. Kushniyarov, E. Herdtweck, K. Meyer, S. Schneider* Angew. Chem. 2010, 122, 7728; Angew. Chem. Int. Ed. 2010, 49, 7566.

"Hydrogen Generation from Small Molecules using Bifunctional Ruthenium Complexes." A. Friedrich, M. Drees, J. Schmedt auf der Günne, S. Schneider* Prep. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2010, 55, 278.

"Ruthenium Complexes with Cooperative PNP-pincer Amino, Amido, Imino, and Enamido Ligands: Facile Ligand Backbone Functionalization Processes." A. Friedrich, M. Drees, M. Käß, E. Herdtweck, S. Schneider* Inorg. Chem., 2010, 49, 5482.

"Facile palladium catalyzed Suzuki-Miyaura coupling in air and water at ambient temperature." A. N. Marziale, S. H. Faul, T. Reiner, S. Schneider, J. Eppinger* Green Chem. 2010, 12, 35.



2009


"Highly Stereoselective Proton/Hydride-Exchange: Assistance of Hydrogen-Bonding for the Heterolytic Splitting of H2." A. Friedrich, M. Drees, J. Schmedt auf der Günne*, S. Schneider* J. Am. Chem. Soc. 2009, 131, 17552.

"Facile C-H Activation of Tetrahydrofurane by an Iridium PNP Pincer Complex." J. Meiners, A. Friedrich, E. Herdtweck, S. Schneider* Organometallics 2009, 28, 6331.

"Ruthenium catalyzed Dimethylamineborane Dehydrogenation: Stepwise Metal Centered Dehydrocyclization." A. Friedrich, M. Drees, S. Schneider* Chem Eur. J. 2009, 15, 10339.

"Acceptorless Dehydrogenation of Alcohols: Perspectives for Synthesis and Hydrogen-Storage." A. Friedrich, S. Schneider* ChemCatChem 2009, 1, 72.

"Palladium PNP Dialkylamides: Synthesis, Structural Characterization and Reactivity." A. N. Marziale, E. Herdtweck, J. Eppinger, S. Schneider* Inorg. Chem. 2009, 48, 3699.

"Highly Efficient Ammonian-Borane Dehydrogenation catalyzed by Ruthenium PNP Pincer complexes." M. Käß, A. Friedrich, M. Drees, S. Schneider* Angew. Chem. 2009, 121, 922; Angew. Chem. Int. Ed., 2009, 48, 905.

"Iridium Olefin Complexes bearing Dialkylamino/amido PNP Pincer Ligands: Synthesis, Reactivity, and Solution Dynamics." A. Friedrich, R. Ghosh, R. Kolb, E. Herdtweck, S. Schneider* Organometallics 2009, 28, 708.



2008 - 2000


"Ligand Metalation in an Iridiumtris(diisopropylphosphinomethyl)borato complex: Synthesis, Molecular Structure, and Reactivity." M. R. Buchner, E. Herdtweck, S. Schneider* J. Organomet. Chem. 2008, 693, 3943.

"Tris(phosphino)borato Silver(I) Complexes as Precursors for Metallic Silver Aerosol-Assisted Chemical Vapor Deposition." M. McCain, S. Schneider, M. R. Salata, T. J. Marks* Inorg. Chem. 2008, 47, 2534.

"Copper(I) tert-Butylthiolato Clusters as Single-Source Precursors for Chalcocite Thin Films: Film Growth and Microstructure Control." S. Schneider, J. R. Ireland, M. C. Hersam, T. J. Marks* Chem. Mater. 2007, 19, 2780.

"Copper(I) tert-Butylthiolato Clusters as Single-Source Precursors for Chalcocite Thin Films: Precursor Chemistry in Solution and the Solid State." S. Schneider, A. Dzudza, G. Raudaschl-Sieber, T. J. Marks* Chem. Mater. 2007, 19, 2768.

"Mixed diketonate thiolate copper(I) precursors for materials synthesis: Control of Cu2S forming thermolysis pathways by manipulating Lewis acid and base cluster building blocks." S. Schneider, J. Roberts, M. R. Salata, T. J. Marks* Angew. Chem. 2006, 118, 1765.

"Growth of highly oriented chalcocite thin films on glass by aerosol-assisted spray pyrolysis using a new single-source copper thiolate precursor." S. Schneider, Y. Yang, T. J. Marks* Chem. Mater. 2005, 17, 4286.

"Metallorganische Chemie des Chroms in ungewoehnlichen Oxidationsstufen und Koordinationsgeometrien" A. C. Filippou*, S. Schneider Humboldt Spektrum 2003, 2-3, 36.

"[Na(THF)2Cr(N3N)]: The first trigonal monopyramidal Chromium(II) complex." A. C. Filippou*, S. Schneider, G. Schnakenburg Inorg. Chem. 2003, 42, 6974.

"A Pair of Remarkably Stable Mononuclear Chromium(III) and Chromium(IV) Hydrides." A. C. Filippou*, S. Schneider, G. Schnakenburg Angew. Chem. 2003, 115, 4624.

"Unusually Stable Chromium(IV) Alkyls Bearing a Triamidoamine Ligand." A. C. Filippou*, S. Schneider Organometallics 2003, 22, 3010.

"Synthesis and Molecular Structures of Chromium(IV) Halides and Pseudohalides Bearing a Triamidoamine Ligand." A. C. Filippou*, S. Schneider, B. Ziemer Eur. J. Inorg. Chem. 2002, 2928.

"Triamidoamine Complexes of Chromium(III) and Chromium(IV)." S. Schneider, A. C. Filippou* Inorg. Chem. 2001, 40, 4674.

"ortho-Metalation of Triarylphosphane at Cobalt and Template Synthesis of Chelating 2-(Diarylphosphanyl)aroyl Ligands." H.–F. Klein*, S. Schneider, M. He, U. Floerke, H.-J. Haupt Eur. J. Inorg. Chem. 2000, 2295.