Catalysis for Sustainable Synthesis (CaSuS)

Publications
2017


  • I. Koehne, N. Graw, T. Teuteberg, R. Herbst-Irmer, D. Stalke: "Introducing NacNac-Like Bis(4,6-isopropylbenzoxazol-2-yl)methanide in s-Block Metal
    Coordination",
    Inorg. Chem. 2017, 56, 14968-14978.
    doi: 10.1021/acs.inorgchem.7b02276

  • M. Schütze, S. Dechert and F. Meyer: "Highly Active and Readily Accessible Proline-Based Dizinc Catalyst for CO2/Epoxide Copolymerization",
    Chem. Eur. J. 2017, 23, 16472-16475.
    doi: 10.1002/chem.201704754

  • I. Koehne, S. Bachmann, R. Herbst-Irmer and D. Stalke: "A Water-Containing Organopotassium Compound Based on Bis(4,6-tBu-benzoxazol-2-yl)methanide and Its Unexpected Stability to Hydrolysis",
    Angew. Chem. Int. Ed. 2017, 56, 15141-15145.
    doi: 10.1002/anie.201706316

  • I. Koehne, S. Bachmann, T. Niklas, R. Herbst-Irmer and D. Stalke: "A Novel Bulky Heteroaromatic-Substituted Methanide Mimicking NacNac: Bis(4,6-tert-butylbenzoxazol-2-yl)methanide in s-Block Metal Coordination",
    Chem. Eur. J. 2017, 23, 13141-13149.
    doi: 10.1002/chem.201702378

  • I. Koehne, R. Herbst-Irmer and D. Stalke: "Bis(4-methylbenzoxazol-2-yl)methanide in s-Block Metal Coordination",
    Eur. J. Inorg. Chem. 2017, 27, 3322-3326.
    doi: 10.1002/ejic.201700501

  • M. Kolter, K. Böck, K. Karaghiosoff and K. Koszinowsk: "Anionische Palladium(0)- und Palladium(II)-At-Komplexe",
    Angew. Chem. Int. Ed. 2017, 56, 13244-13248.
    doi: 10.1002/anie.201707362

  • Ò. Àrias, K. Brandhorst, D. Baabe, M. Freytag, P. G. Jonesa and M. Tamm: "Formation of paramagnetic metallacyclobutadienes by reaction of diaminoacetylenes with molybdenum alkylidyne complexes",
    Dalton Trans. 2017, 46, 4737-4748.
    doi: 10.1039/C7DT00305F/

  • Z. Ruan, N. Sauermann, E. Manoni, L. Ackermann: "Manganese-Catalyzed C?H Alkynylation: Expedient Peptide Synthesis and Modification",
    Angew. Chem. Int. Ed. 2017, 56, 3172-3176.
    doi: 10.1002/anie.201611118 Both authors contributed equally.

  • S. Warratz, D. J. Burns, C. Zhu, K. Korvorapun, T. Rogge, J. Scholz, C. Jooss, D. Gelman, L. Ackermann: "meta-C-H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis",
    Angew. Chem. Int. Ed. 2017, 56, 1557-1560.
    doi: 10.1002/anie.201609014

  • S. De Sarkar, N. Y. P. Kumar, L. Ackermann: "Ruthenium(II)Biscarboxylate-Catalyzed Borylations of C(sp2)-H and C(sp3)-H Bonds",
    Chem. Eur. J. 2017, 23, 84-87.
    doi: 10.1002/chem.201604943
    Both authors contributed equally.



2016



  • X. Tian, F. Yang, D. Rasina, M. Bauer, S. Warratz, F. Ferlin, L. Vaccaro, L. Ackermann: "C-H Arylations of 1,2,3-Triazoles by Reusable Heterogeneous Palladium Catalysts in Biomass-Derived gamma-Valerolactone",
    Chem. Commun. 2016, 52, 9777-9780.
    doi: 10.1039/C6GC01393G

  • D. Rasina, A. Kahler-Quesada, S. Ziarelli, S. Warratz, H. Cao, S. Santoro, L. Ackermann, L. Vaccaro: "Heterogeneous Palladium-Catalysed Catellani Reaction in Biomass-Derived gamma-Valerolactone",
    Angew. Chem. Int. Ed. 2016, 18, 5025-5030.
    doi: 10.1002/anie.201600490

  • N. Y. P. Kumar, A. Bechtoldt, K. Raghuvanshi, L. Ackermann: "Ruthenium(II)-Catalyzed Decarboxylative C-H-Activation: Versatile Routes to meta-Alkenylated Arenes",
    Angew. Chem. Int. Ed. 2016, 55, 6929-6932.
    doi: 10.1002/anie.201600490

  • M. Kolter, K. Koszinowski: "Stability and Unimolecular Reactivity of Palladate(II) Complexes [LnPdR3]- (L=Phosphine, R=Organyl, n = 0 and 1)",
    Chem. Eur. J. 2016, 22, 15744-15750.
    doi: 10.1002/chem.201603431

  • Roc Matheu, Sven Neudeck, Franc Meyer, Xavier Sala, and Antoni Llobet: "Foot of the Wave Analysis for Mechanistic Elucidation and Benchmarking Applications in Molecular Water Oxidation Catalysis",
    ChemSusChem 2016, 9, 3361-3369.
    doi: 10.1002/cssc.20160128

  • S. Smolne, M. Buback, S. Demeshko, K. Matyjaszewski, F. Meyer, H. Schroeder, A. Simakova: "Kinetics of Fe-Mesohemin-(MPEG500)2 Mediated RDRP in Aqueous Solution",
    Macromolecules 2016, 49, 8088-8097.
    doi: 10.1021/acs.macromol.6b01774

  • R. Mei, H. Wang, S. Warratz, S. A. Macgregor, L. Ackermann: "Cobalt-Catalyzed Oxidase C-H/N-H Alkyne Annulation: Mechanistic Insights and Access to anti-Cancer Agents",
    Chem. Eur. J. 2016, 22, 6759-6763.
    doi: 10.1002/chem.201601101

  • S. Neudeck, S. Maji, I. Lopez, S. Dechert, J. Benet-Buchholz, A. Llobet, F. Meyer: "Establishing the Family of Diruthenium Water Oxidation Catalysts Based on the Bis(bipyridyl)pyrazolate Ligand System",
    Inorg. Chem. 2016, 55, 2508-2521.
    doi: 10.1021/acs.inorgchem.5b02869

  • J. I. Schweizer, M. G. Scheibel, M. Diefenbach, F. Neumeyer, C. Würtele, N. Kulminskaya, R. Linser, N. Auer, S. Schneider, M. C. Holthausen: "A Disilene Base Adduct with a Dative Si-Si Single Bond",
    Angew. Chem. Int. Ed. 2016, 55, 1782-1786.
    doi: 10.1002/anie.201510477

  • A. Bechtoldt, C. Tirler, K. Raghuvanshi, S. Warratz, C. Kornhaaß, L. Ackermann: "Ruthenium Oxidase Catalysis for Site-Selective C-H Alkenylations with Ambient O2 as the Sole Oxidant",
    Angew. Chem. Int. Ed. 2016, 55, 264-267.
    doi: 10.1002/anie.201507801

  • A. Lemke, C. Ducho: "Synthesis of Deuterium-Labelled 3-Hydroxy-L-arginine: Comparative Studies on Different Protecting-Group Strategies",
    Eur. J. Org. Chem. 2016, 87-98.
    doi: 10.1002/ejoc.201501109

  • L.F. Tietze, S. Jackenkroll, D. Ganapathy, J.R. Reiner: "Formal Synthesis of (-)-Siccanin Using an Enantioselective Domino Wacker/Carbonylation/Methoxylation Reaction",
    Synlett 2016, 27, 96-100.
    doi: 10.1055/s-0035-1560752

  • D. Zell, S. Warratz, D. Gelman, S. J. Garden, L. Ackermann: "Single-Component Phosphinous Acid Ruthenium(II) Catalysts for Versatile C-H Activations by Metal-Ligand Cooperation",
    Chem. Eur. J. 2016, 22, 1248-1252.
    doi: 10.1002/chem.201504851



2015



  • N. Sauermann, M. J. González, L. Ackermann: "Cobalt(III)-Catalyzed C-H Alkynylation with Bromoalkynes under Mild Conditions",
    Org. Lett. 2015, 17, 5316-5319.
    doi: 10.1021/acs.orglett.5b02678

  • M. Pawliczek, T. F. Schneider, C. Maaß, D. Stalke, D. B. Werz: "Formal anti-Carbopalladation Reactions of Non-Activated Alkynes: Requirements, Mechanistic Insights, and Applications",
    Angew. Chem. Int. Ed 2015, 54, 4119-4123.
    doi: 10.1002/anie.201411210

  • E. Carl, D. Stalke: "Novel germanium(II) and tin(II) halide complexes containing the triimido sulfur(VI) phosphanyl ligand",
    Eur. J. Inorg. Chem. 2015 2052-2056.
    doi: 10.1002/ejic.201500074

  • A. Glüer, M. Förster, V. R. Celinski, J. Schmedt auf der Günne, M. C. Holthausen, S. Schneider: "Highly Active Iron Catalyst for Ammonia Borane Dehydrocoupling at Room Temperature",
    ACS Catalysis 2015, 5, 7214-7217.
    doi: 10.1021/acscatal.5b02406

  • C. Schiwek, J. Meiners, M. Förster, C. Würtele, M. Diefenbach, M. C. Holthausen, S. Schneider: "Oxygen Reduction with a Bifunctional Iridium Dihydride Complex",
    Angew. Chem. Int. Ed. 2015, 54, 1-6.
    doi: 10.1002/anie.201504369

  • M. G. Scheibel, J. Abbenseth, M. Kinauer, F. W. Heinemann, C. Würtele, B. de Bruin, S. Schneider: "Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, Imide, and Nitride Species",
    Inorg. Chem. 2015, 54, 9290-9302.
    doi: 10.1021/acs.inorgchem.5b00829

  • S. Berardi, L. Francàs, S. Neudeck, S. Maji, J. Benet-Buchholz, F. Meyer, A. Llobet: "Efficient Light-Driven Water Oxidation Catalysis by Dinuclear Ruthenium Complexes'",
    ChemSusChem 2015, 8, 3688-3696.
    doi: 10.1002/cssc.201500798

  • J. Li, S. Warratz, D. Zell, S. De Sarkar, E. E. Ishikawa, L. Ackermann: "N-Acyl Amino Acid Ligands for Ruthenium(II)-catalyzed meta-C-H tert-Alkylation with Removable Auxiliaries",
    J. Am. Chem. Soc. 2015, 137, 13894-13901.
    doi: 10.1021/jacs.5b08435

  • M. Han, Y. Luo, B. Damaschke, L. Gomez, X. Ribas, A. Jose, P. Peretzki, M. Seibt, G. H. Clever: "Light-controlled Interconversion between a Self-assembled Triangle and a Rhombicuboctahedral Sphere",
    Angew. Chem. Int. Ed. 2015, 55, 445-449.
    doi: 10.1002/anie.201508307

  • B. Milde, M. Leibeling, A. Hecht, A. Visscher, D. Stalke, P. G. Jones, J. Grunenberg, D. B. Werz: "Oligoene-Based -Helicenes or Dispiranes Winding Up Oligoyne Chains by a Multiple Carbopalladation/Stille/(Electrocyclization) Cascade",
    Chem. Eur. J. 2015, 21, 16136-16146.
    doi: 10.1002/chem.201501797

  • N. Förster, S. Schmidt, P. Vana: "Tailoring Confinement: Nano-Carrier Synthesis via Z-RAFT Star Polymerization",
    Polymers 2015, 7, 695-716.
    doi: 10.3390/polym7040695

  • A. Glüer, B. Askevold, B. Schluschaß, F. W. Heinemann, S. Schneider: "Electron-rich, Nitrido-bridged Ruthenium Complexes",
    Z. Allg. Anorg. Chem. 2015, 641, 49-51.
    doi: 10.1002/zaac.201400166

  • E. Carl, S. Demeshko, F. Meyer, D. Stalke: "Triimidosulfonates as Acute Bite-Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a CoII Complex",
    Chem. Eur. J. 2015, 21, 10109-10115.
    doi: 10.1002/chem.201406083

  • A. C. Sander, S. Maji, L. Francàs, T. Böhnisch, S. Dechert, A. Llobet, F. Meyer: "Highly Efficient Binuclear Ruthenium Catalyst for Water Oxidation",
    ChemSusChem 2015, 8, 1697-1702.
    doi: 10.1002/cssc.201403344

  • M. Moselage, N. Sauermann, J. Koeller, W. Liu, D. Gelman, L. Ackermann: "Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage",
    Synlett 2015, 1596-1600.
    doi: 10.1055/s-0034-1379927

  • H. Schroeder, J. Buback, S. Demeshko, K. Matyjaszewski, F. Meyer, M. Buback: "Speciation Alalysis in Iron-Mediated ATRP Studied via FT-Near-IR and Mössbauer Spectroscopy",
    Macromolecules 2015, 48, 1981-1990.
    doi: 10.1021/acs.macromol.5b00023

  • M. Moselage, N. Sauermann, S. C. Richter, L. Ackermann: "C-H Alkenylations with Alkenyl Acetates, Phosphates, Carbonates, and Carbamates by Cobalt Catalysis at 23°C",
    Angew. Chem. Int. Ed. 2015, 54, 6352-6355.
    doi: 10.1002/anie.201412319

  • S. Warratz, C. Kornhaaß, A. Cajaraville, B. Niepötter, D. Stalke, L. Ackermann: "Ruthenium(II)-Catalyzed C-H Activation/Alkyne Annulation with O2 as the Sole Oxidant by Weak-Coordination",
    Angew. Chem. Int. Ed. 2015, 54, 5513-5517.
    doi: 10.1002/anie.201500600

  • S. Primpke, P. Vana: "Modeling of Catalyzed Chain Growth (CCG) Polymerization of Styrene-d8 using Cp*2ZrCl2 and Dibenzylmagnesium",
    Macromol. Theory Simul. 2015, 24, 232-247.
    doi: 10.1002/mats.201400087




2014



  • A.-C. Pöppler, M. Granitzka, R. Herbst-Irmer, Y.-S. Chen, B. B. Iversen, M. John, R. A. Mata, D. Stalke: "Characterization of a Multicomponent Lithium Lithiate from a Combined X-Ray Diffraction, NMR Spectroscopy, and Computational Approach",
    Angew. Chem. Int. Ed. 2014, 53, 13282-13287.
    doi: 10.1002/anie.201406320

  • E. Carl, D. Stalke: "Polyimido Sulfur(VI) Phosphanyl Ligand in Metal Complexation",
    Chem. Eur. J. 2014, 20, 15849-15854.
    doi: 10.1002/chem.201404860

  • H. Schroeder, M. Buback, K. Matyjaszewski: "Pressure Dependence of Iron-Mediated Methyl Methacrylate ATRP in Different Solvent Environments",
    Macromol. Chem. Phys. 2014, 215, 44-53.
    doi: 10.1002/macp.201300505

  • F. Yang, L. Ackermann: "Dehydrative C-H/N-OH Functionalizations in H2O by Ruthenium(II)-Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight",
    J. Org. Chem. 2014, 79, 12070-12082.
    doi: 10.1021/jo501884v

  • F. Yang, K. Rauch, K. Kettelhoit, L. Ackermann: "Aldehyde-Assisted Ruthenium(II)-Catalyzed C-H Oxygenations",
    Angew. Chem. Int. Ed. 2014, 53, 11285-11288.
    doi: 10.1002/anie.201405647

  • C. Kornhaaß, C. Kuper, L. Ackermann: "Ferrocenylalkynes for Ruthenium-Catalyzed Isohypsic C-H/N-O Bond Functionalizations",
    Adv. Synth. Catal. 2014, 356, 1619-1624.
    doi: 10.1002/adsc.201301156

  • T. Guo, S. Dechert, F. Meyer: "Dinuclear Palladium Complexes of Pyrazole-Bridged Bis(NHC) Ligands: A Delicate Balance between Normal and Abnormal Carbene Coordination",
    Organometallics 2014, 33, 5145-5155.
    doi: 10.1021/om500351j

  • A. Walli, S. Dechert, M. Bauer, S. Demeshko, F. Meyer: "BOX Ligands in Biomimetic Copper-Mediated Dioxygen Activation - A Hemocyanin Model",
    Eur. J. Inorg. Chem. 2014, 4660-4676.
    doi: 10.1002/ejic.201402378

  • M. Cayir, L. T. Ghoochany, A. Walli, M. Busch, Y. Sun, F. Meyer, S. Bräse, W. R. Thiel: "C-H Activation at a Bidentate Ligand Coordinated to Palladium(II) - an Electrophilic Attack Supported by an External Base",
    Eur. J. Inorg. Chem. 2014, 2618-2624.
    doi: 10.1002/ejic.201402149

  • A. Wolpers, P. Vana: "UV Light as External Switch and Boost of Molar-Mass Control in Iodine-Mediated Polymerization",
    Macromolecules 2014, 47, 954-963.
    doi: 10.1021/ma402537r

  • M. Han, D. M. Engelhard, G. H. Clever: "Self-Assembled Coordination Cages based on Banana-shaped Ligands",
    Chem. Soc. Rev. 2014, 43, 1848-1860.
    doi: 10.1039/C3CS60473J

  • M. Han, R. Michel, G. H. Clever: "Rational Design of a Face-Centered Square-Cuboid Coordination Cage",
    Chem. Eur. J. 2014, 20, 10640-10644.
    doi: 10.1002/chem.201303181

  • S. Primpke, A. Deinert, F. Ehlers, P. Vana: "A Kinetic Investigation of the Initialization of Catalyzed Chain Growth of Styrene: The Reaction of Cp*2ZrCl2 with Dibenzylmagnesium",
    Macromol. Chem. Phys. 2014, 250, 544-554.
    doi: 10.1002/macp.201300710

  • S. Neudeck, S. Maji, I. López, S. Meyer, F. Meyer, A. Llobet: "New Powerful and Oxidatively Rugged Dinuclear Ru Water Oxidation Catalyst: Control of Mechanistic Pathways by Tailored Ligand Design",
    J. Am. Chem. Soc. 2014, 136, 24-27.
    doi: 10.1021/ja409974b




2013



  • M. G. Scheibel, Y. Wu, A. C. Stückl, L. Krause, E. Carl, D. Stalke, B. de Bruin, S. Schneider: "Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium",
    J. Am. Chem. Soc. 2013, 135, 17719-17722.
    doi: 10.1021/ja409764j

  • M. Ainooson, F. Meyer: "Bimetallic Approaches in Olefin Polymerization and Metathesis",
    Comprehensive Inorganic Chemistry II (Eds.: J. Reedijk, K. Poeppelmeier); Elsevier: Oxford, UK, 2013, Vol. 8, 433-458.

  • M. Leibeling, D. B. Werz: "Flexible synthesis of anthracycline aglycone mimics via domino carbopalladation reactions",
    Beilstein J. Org. Chem. 2013, 9, 2194-2201.
    doi: 10.3762/bjoc.9.258

  • J. Hey, D. M. Andrada, R. Michel, R. A. Mata, D. Stalke: "Strong Intermolecular Interactions Shaping a Small Piano-Stool Complex",
    Angew. Chem. Int. Ed. 2013, 52, 10365-10369.
    doi: 10.1002/anie.201304498

  • A.-C. Pöppler, S. Frischkorn, D. Stalke, M. John: "Toluene and Lithium Amide Diffusion into Polystyrene: A Slice-Selective NMR-Spectroscopic Study",
    ChemPhysChem 2013, 14, 3103-3107.
    doi: 10.1002/cphc201300609

  • C. Maaß, D. M. Andrada, R. A. Mata, R. Herbst-Irmer, D. Stalke: "Effects of Metal Coordination on the pi-System of the 2,5-Bis-{(pyrrolidino)-methyl}-pyrrole Pincer Ligand",
    Inorg. Chem. 2013, 52, 9539-9548.
    doi: 10.1021/ic401192x

  • M. G. Scheibel, I. Klopsch, H. Wolf, P. Stollberg, D. Stalke, S. Schneider: "Thionitrosyl- and Selenonitrosyliridium Complexes",
    Eur. J. Inorg. Chem. 2013, 20, 3454-3457.
    doi: 10.1002/ejic.201300409

  • N. Förster, A.-C. Pöppler, D. Stalke, P. Vana: "Photocrosslinkable Star Polymer via RAFT-Copolymerizations with N-Ethylacrylate-3,4-dimethylmaleimide",
    Polymers 2013, 5, 706-729.
    doi: 10.3390/polym5020706

  • A. Walli, S. Dechert, F. Meyer: "Tautomerism in Bis(oxazoline)s",
    Eur. J. Org. Chem. 2013, 7044-7049.
    doi: 10.1002/ejoc.201301282

  • N. Y. P. Kumar, R. Jeyachandran, L. Ackermann: "C(sp3)-H Bond Arylations Catalysed by Well-Defined [Ru(O2CMes)2(p-cymene)]",
    J. Org. Chem. 2013, 78, 4145-4152.
    doi: 10.1021/jo400658d

  • L. F. Tietze, S. Jackenkroll, C. Raith, D. A. Spiegl, J. R. Reiner, M. C. Ochoa Campos: "Enantioselective Total Synthesis of (-)-Diversonol",
    Chem. Eur. J. 2013, 19, 4876-4882.
    doi: 10.1002/chem.201204037

  • N. Hofmann, L. Ackermann: "meta-Selective C-H Bond Alkylation with Secondary Alkyl Halides",
    J. Am. Chem. Soc. 2013, 135, 5877-5884.
    doi: 10.1021/ja401466y

  • E. Diers, N. Y. P. Kumar, T. Mejuch, I. Marek, L. Ackermann: "Carboxylate-assisted ruthenium(II)-catalyzed C-H arylations of 5-aryl tetrazoles: step-economical access to Valsartan",
    Tetrahedron 2013, 69, 4445-4453.
    doi: 10.1016/j.tet.2013.01.006

  • T. K. Saha, H. Frauendorf, M. John, S. Dechert, F. Meyer: "Efficient Oxidative Degradation of Azo Dyes by a Water-Soluble Manganese Porphyrin Catalyst",
    ChemCatChem 2013, 5, 796-805.
    doi: 10.1002/cctc.201200475

  • F. Yang, L. Ackermann: "Ruthenium-Catalyzed C-H Oxygenation on Aryl Weinreb Amides",
    Org. Lett. 2013, 15, 718-720.
    doi: 10.1021/ol303520h

  • Y. Wang, H. Schroeder, J. Morick, M. Buback, K. Matyjaszewski: "High-Pressure Atom Transfer Radical Polymerization of n-Butyl Acrylate",
    Macromol. Rapid Commun. 2013, 34, 604-609.
    doi: 10.1002/marc.201200752

  • Y. Wang, N. Soerensen, M. Zhong, H. Schroeder, M. Buback, K. Matyjaszewski: "Improving the "Livingness" of ATRP by Reducing Cu Catalyst Concentration",
    Macromolecules 2013, 46, 683-691.
    doi: 10.1021/ma3024393

  • M. Han, R. Michel, B. He, Y.-S. Chen, D. Stalke, M. John, G. H. Clever: "Light-triggered Guest Uptake and Release by a Photochromic Coordination Cage",
    Angew. Chem. Int. Ed. 2013, 51, 1319-1323.
    doi: 10.1002/anie.201207373




2012



  • T. Guo, S. Dechert, S. Meyer, F. Meyer: "Convenient Synthetic Route to Palladium Complexes of Unconventional N-Heterocyclic Carbenes Derived from Pyridazine and Phthalazine",
    Organometallics 2012, 31, 8537-8543.
    doi: 10.1021/om300899r

  • N. Soerensen, J. Barth, M. Buback, J. Morick, H. Schroeder, K. Matyjaszewski: "SP-PLP-EPR Measurement of ATRP Deactivation Rate",
    Macromolecules 2012, 45, 3797-3801.
    doi: 10.1021/ma300420j

  • H. Schroeder, D. Yalalov, M. Buback, K. Matyjaszewski: "Activation-Deactivation Equilibrium Associated With Iron-Mediated Atom-Transfer Radical Polymerization up to High Pressure",
    Macromol. Chem. Phys. 2012, 213, 2019-2026.
    doi: 10.1002/macp.201200244



  • M. Han, J. Hey, W. Kawamura, D. Stalke, M. Shionoya, G. H. Clever: "An Inclusion Complex of Hexamolybdate inside a Supramolecular Cage and its Structural Conversion",
    Inorg. Chem. 2012, 51, 9574-9576.
    doi: 10.1021/ic301359n



  • J. Li, C. Kornhaaß, L. Ackermann: "Ruthenium-catalyzed oxidative C-H alkenylation of aryl carbamates",
    Chem. Commun. 2012, 48, 11343-11345.
    doi: 10.1039/C2CC36196E



  • C. Kornhaaß, J. Li, L. Ackermann: "Cationic Ruthenium Catalysts for Alkyne Annulations with Oximes by C-H/N-O Functionalizations",
    J. Org. Chem. 2012, 77, 9190-9198.
    doi: 10.1021/jo301768b



  • L. F. Tietze, T. Hungerland, C. Depken, C. Maaß, D. Stalke: "Palladium-Catalyzed Domino-Carbopalladation/CH-Activation for the Synthesis of Tetrasubstituted Alkenes Bearing Five- and Seven-Membered Rings",
    Synlett 2012, 23, 2516-2520.
    doi: 10.1055/s-0032-1317325



  • A.-C. Pöppler, H. Keil, D. Stalke, M. John: "7Li Residual Quadrupolar Couplings (RQCs) as a Powerful Tool to Identify Organolithium Aggregation",
    Angew. Chem. Int. Ed. 2012, 51, 7843-7846.
    doi: 10.1002/ange.201202116



  • A. P. Singh, H. W. Roesky, E. Carl, D. Stalke, J.-P. Demers, A. Lange: "Lewis Base Mediated Autoionization of GeCl2 and SnCl2",
    J. Am. Chem. Soc. 2012, 134, 4998-5003.
    doi: 10.1021/ja300563g



  • S. Freye, J. Hey, A. Torras-Galán, D. Stalke, R. Herbst-Irmer, M. John, G. H. Clever: "Allosteric Binding of Halide Anions by a New Dimeric Interpenetrated Coordination Cage",
    Angew. Chem. Int. Ed. 2012, 51, 2191-2194.
    doi: 10.1002/anie.201107184



  • R. Azhakar, R. S. Ghadwal, H. W. Roesky, J. Hey, D. Stalke: "Facile Access to Transition-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand",
    Chem. Asian J. 2012, 7, 528-533.
    doi: 10.1002/asia.201100722



  • M. Leibeling, D. B. Werz: "Winding up Alkynes: A Pd-Catalyzed Tandem-Domino Reaction to Chiral Biphenyls",
    Chem. Eur. J. 2012, 18, 6138-6141.
    doi: 10.1002/chem.201200175



  • M. Leibeling, M. Pawliczek, D. Kratzert, D. Stalke, D. B. Werz: "A Ridge Walk Between Reaction Modes: An Unprecedented Pd-Catalyzed Domino Sequence of Divinyl-Substituted Bromoarenes",
    Org. Lett. 2012, 14, 346-349.
    doi: 10.1021/ol2030923



  • L. Ackermann, E. Diers, A. Manvar: "Ruthenium-Catalyzed C-H Bond Arylations of Arenes Bearing Removable Directing Groups via Six-Membered Ruthenacycles",
    Org. Lett. 2012, 14, 1154-1157.
    doi: 10.1021/ol3000876



  • L. Ackermann, C. Kornhaaß, Y. Zhu: "Palladium-Catalyzed Direct C-H Bond Alkynylations of Heteroarenes Using gem-Dichloroalkenes",
    Org. Lett. 2012, 14, 1824-1826.
    doi: 10.1021/ol300514d



  • M. Granitzka, A.-C. Pöppler, E. K. Schwarze, D. Stern, T. Schulz, M. John, R. Herbst-Irmer, S. K. Pandey, D. Stalke: "Aggregation of Donor Base Stabilized 2-Thienyllithium in a Single Crystal and in Solution: Distances from X-ray Diffraction and the Nuclear Overhauser Effect",
    J. Am. Chem. Soc. 2012, 134, 1344-1351.
    doi: 10.1021/ja210382c



  • A.-C. Pöppler, M. M. Meinholz, H. Faßhuber, A. Lange, M. John, D. Stalke: "Mixed Crystalline Lithium Organics and Interconversion in Solution",
    Organometallics 2012, 31, 42-45.
    doi: 10.1021/om2010639




    2011



    • S. S. Sen, J. Hey, M. Eckhardt, R. Herbst-Irmer, E. Maedl, R. A. Mata, H. W. Roesky, M. Scheer, D. Stalke: "A Stable Cation of a CSi3P Five-Membered Ring with a Weakly Coordinating Chloride Anion",
      Angew. Chem. Int. Ed. 2011, 50, 12510-12513.
      doi: 10.1002/anie.201104146

    • M. M. Meinholz, E. Carl, E. Kriemen, D. Stalke: "Peroxide solvation by a toroidal lithium inverse crown ether complex assembled by multidentate polyimido sulfonates",
      Chem. Commun. 2011, 47, 10948-10950.
      doi: 10.1039/c1cc14466a

    • C. Brand, M. Granitzka, D. Stalke, D. B. Werz: "Reducing the conformational flexibility of carbohydrates: Locking the 6-hydroxyl group by cyclopropanes",
      Chem. Commun. 2011, 47, 10782-10784.
      doi: 10.1039/c1cc14025f

    • C. K. Ullal, S. Primpke, R. Schmidt, U. Böhm, A. Egner, P. Vana, S. W. Hell: "Flexible Microdomain Specific Staining of Block Copolymers for 3D Optical Nanoscopy",
      Macromolecules 2011, 44, 7508-7510.
      doi: 10.1021/ma201504f

    • A. Wolpers, G. T. Russell, P. Vana: "The Impact of Band Broadening on Molar-Mass Determination of Narrow-Distribution Polymer by Size-Exclusion Chromatography",
      Macromol. Theory Simul. 2011, 20, 667–674.
      doi: 10.1002/mats.201100038

    • M. Leibeling, B. Milde, D. Kratzert, D. Stalke, D. B. Werz: "Intermolecular Twofold Carbopalladation/Cyclization Sequence to Access Chromans and Isochromans from Carbohydrates",
      Chem. Eur. J. 2011, 17, 9888-9892.
      doi: 10.1002/chem.201101917

    • M. Leibeling, D. B. Werz: "Lichtblicke: Neues aus der Photoredoxkatalyse",
      Nachrichten aus der Chemie 2011, 59, 1063-1067.
      doi: 10.1002/nadc.201190097

    • S. S. Sen, J. Hey, R. Herbst-Irmer, H. W. Roesky, D. Stalke: "Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si-Me Bond Cleavage without a Transition Metal Catalyst",
      J. Am. Chem. Soc. 2011, 133, 12311-12316.
      doi: 10.1021/ja205369h

    • R. Azhakar, R. S. Ghadwal, H. W. Roesky, J. Hey, D. Stalke: "Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone",
      Organometallics 2011, 30, 3853-3858.
      doi: 10.1021/om200388a

    • R. Azhakar, S. P. Sarish, H. W. Roesky, J. Hey, D. Stalke: "Regiospecific C-H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide",
      Organometallics 2011, 30, 2897-2900.
      doi: 10.1021/om200308u

    • R. Azhakar, S. P. Sarish, H. W. Roesky, J. Hey, D. Stalke: "Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene",
      Inorg. Chem. 2011, 50, 5039-5043.
      doi: 10.1021/ic2003035

    • R. Azhakar, S. P. Sarish, G. Tavcar, H. W. Roesky, J. Hey, D. Stalke, D. Koley: "Formation of Silicone Centered Spirocyclic Compounds: Reaction of N-Heterocyclic Stable Silylene with Benzoylpyridine, Diisopropyl Azodicarboxylate, and 1,2-Diphenylhydrazine",
      Inorg. Chem. 2011, 50, 3028-3036.
      doi: 10.1021/ic102566

    • L. Ackermann, A. V. Lygin, N. Hofmann: "Ruthenium-Catalyzed Oxidative Synthesis of 2-Pyridones through C-H/N-H Bond Functionalizations",
      Org. Lett. 2011, 13, 3278-3281.
      doi: 10.1021/ol201244s

    • L. Ackermann, A. V. Lygin, N. Hofmann: "Ruthenium-Catalyzed Oxidative Annulation via C-H/N-H Bond Cleavages",
      Angew. Chem. Int. Ed. 2011, 50, 6379-6382.
      doi: 10.1002/anie.201101943

    • L. Ackermann, S. Barfüßer, C. Kornhaaß, A. R. Kapdi: "C-H Bond Arylations and Benzylations on Oxazol(in)es with a Palladium Catalyst of a Secondary Phosphine Oxide",
      Org. Lett. 2011, 13, 3082-3085.
      doi: 10.1021/ol200986x

    • L. Ackermann, A. R. Kapdi, S. Fenner, C. Kornhaaß, C. Schulzke: "Well-Defined Air-Stable Palladium HASPO Complexes for Efficient Kumada-Corriu Cross-Couplings of (Hetero)Aryl or Alkenyl Tosylates",
      Chem. Eur. J. 2011, 17, 2965-2971.
      doi: 10.1002/chem.201002386

    • L. Ackermann, N. Hofmann, R. Vicente: "Carboxylate-Assisted Ruthenium-Catalyzed Direct Alkylations of Ketimines",
      Org. Lett. 2011, 13, 1875-1877.
      doi: 10.1021/ol200366n

    • A. Wolpers, L. Ackermann, P. Vana: "H-Phosphonic Acid Derivatives as Catalysts for Reversible Chain Transfer Catalyzed Polymerization (RTCP) at Ambient and High Pressure",
      Macromol. Chem. Phys. 2011, 212, 259–265.
      doi: 10.1002/macp.201000623

    • R. Azhakar, G. Tavcar, H. W. Roesky, J. Hey, D. Stalke: "Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct",
      Eur. J. Inorg. Chem. 2011, 475–477.
      doi: 10.1002/ejic.201001188




    2010



    • M. G. Fröhlich, M. M. Nardai, N. Förster, P. Vana, G. Zifferer: "Shielding effects in polymer-polymer reactions, 3. Z-RAFT Star Polymerization under Various Solvent Conditions",
      Polymer 2010, 51, 5122-5134.
      doi: 10.1016/j.polymer.2010.08.054

    • D. C. Koester, M. Leibeling, R. Neufeld, D. B. Werz: "A Pd-Catalyzed Approach to (1→6)-Linked C-Glycosides",
      Org. Lett. 2010, 12, 3934–3937.
      doi: 10.1021/ol101625p

    • M. Leibeling, D. C. Koester, M. Pawliczek, D. Kratzert, B. Dittrich, D. B. Werz: "Hybrids of sugars and aromatics: A Pd-catalyzed modular approach to chromans and isochromans",
      Bioorg. Med. Chem. (Symposium-in-print) 2010, 18, 3656–3667.
      doi: 10.1016/j.bmc.2010.03.004

    • M. Leibeling, D. C. Koester, M. Pawliczek, S. C. Schild, D. B. Werz: "Domino access to highly substituted chromans and isochromans from carbohydrates",
      Nature Chem. Biol. 2010, 6, 199-201 (Highlighted in pp. 174–175).
      doi: 10.1038/nchembio.302

    • A. Lemke, M. Büschleb, C. Ducho: "Concise synthesis of both diastereomers of 3-hydroxy-L-arginine",
      Tetrahedron 2010, 66, 208-214.
      doi: 10.1016/j.tet.2009.10.102

    • S. S. Sen, G. Tavcar, H. W. Roesky, D. Kratzert, J. Hey, D. Stalke: "Synthesis of a Stable Four-Membered Si2O2 Ring and a Dimer with Two Four-Membered Si2O2 Rings Bridged by Two Oxygen Atoms, with Five-Coordinate Silicon Atoms in Both Ring Systems",
      Organometallics 2010, 29, 2343-2347.
      doi: 10.1021/om100164u

    • G. Tavcar, S. S. Sen, H. W. Roesky, J. Hey, D. Kratzert, D. Stalke: "Reactions of a Bis-silylene (LSi-SiL, L = PhC(NtBu)2) and a Heteroleptic Chloro Silylene (LSiCl) with Benzil: Formation of Bis(siladioxolene) and Monosiladioxolene Analogue with Five-Coordinate Silicon Atoms in Both Ring Systems",
      Organometallics 2010, 29, 3930-3935.
      doi: 10.1021/om100581u